Thursday, 25 June 2015

OXIDATION AND REDUCTION: REDOX

OXIDATION AND REDUCTION: REDOX

Redox-       Is when oxidation and reduction are taking place at the same time(simultaneously) .
Oxidation-  Is the loss of electrons or oxidation is said to occur when there is an increase in oxidation                     state.
Reduction-   Is the gain of electrons or when there is a decrease in oxidation state .

Cu2+ + Zn --> Cu + Zn2+
For the example given above,Zn has been oxidised (lost electrons ) and Cu has been reduced (gain electrons ).
Remember when a specie losses electron(s) it becomes positively charged and when a specie gains electron(s) it becomes negatively charged .

OXIDATION STATES
Rules

  • All elements in their standard state have zero(0) oxidation state .example Na ,Cl2
  • Na+ has oxidation state of +1 and Mg2+ has oxidation state of +2
  • Cl- has oxidation state of -1 
  • Hydrogen has oxidation state of +1 except in the hydrides where it is -1
How to find the oxidation states of elements in a compound 
Eg  1.find the ox of c in Co2 
C -4 =0             note : O has ox of -2 and there are two molecules of it so the total oxidation state is 
                                  2 * -2 = -4 
C = +4

2. what is the oxidation state of 
 N in No3 - ?                                           3.Mn in MnO4 -
N- (3*2)= -1                                               Mn -(2*4) = -1
N-6 = -1                                                      Mn -8 = -1
N= -1+6                                                      Mn = -1 +8
N= +5                                                         Mn =+7

4.S in SO42− 
S -(2*4) = -2 
S-8= -2
S= -2 +8 
S= +6

Role of oxidation state in naming species 
Manganese(iv) oxide -Mn has +4 oxidation state in MnO2 hence the name 
Sulphur (vi) oxide -    S has + 6 oxidation state 
dichromate (vi)    -      Cr has oxidation state of +6